MODELLING OF ELECTRICAL CONDUCTIVITY OF THE SYSTEMS BASED ON POLYETHERS AND CARBON NANOTUBES

E.A. Lysenkov, V.V. Klepko

Èlektron. model. 2018, 38(1):113-124
https://doi.org/10.15407/emodel.38.01.113

ABSTRACT

The basic theoretical models of electrical conductivity of polymeric nanocomposites and their accordance to experimental results are analyzed for the polyether-carbon nanotubes (CNT) systems using the methods of mathematical simulation. It is shown that the theoretical Scarisbrick, McCullough and Keith models well describe an experiment only in the area of concentrations larger than the percolation threshold. It is discovered that a sigmoidal model, which takes into account the existence of percolation threshold, well describes experimental data of electrical conductivity of the polyether-CNT systems in the wide range of concentrations.

KEYWORDS

percolation behavior, polymer nanocomposites, electrical conductivity, carbon nanotubes.

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